Hanna HI4004 Calcium Ion Selective Electrode – Polymer Membrane Half-Cell Sensor for Precise Calcium Ion Detection
The Hanna HI4004 Calcium Half-Cell Ion Selective Electrode is a polymer membrane ion-selective electrode (ISE) designed to measure calcium ion (Ca²⁺) concentrations in aqueous solutions. This half-cell configuration requires pairing with a reference electrode for a complete measurement system. It is ideal for environmental monitoring, agriculture, food and beverage quality control, and academic laboratories.
Capable of detecting calcium levels from 1 M to 3 × 10⁻⁶ M (40080 ppm to 0.12 ppm), the HI4004 provides stable, linear response across a practical pH range, making it an essential tool for routine calcium analysis in various matrices.
Key Features
Selective Calcium Ion Measurement
Reliable determination of free calcium ions in solution
Measurement range: 40080 ppm to 0.12 ppm (1 M to 3 × 10⁻⁶ M)
Polymer Membrane Technology
Incorporates a calcium-selective polymer membrane for consistent sensitivity and long lifespan
Delivers a slope of approximately +28 mV per decade of concentration
Designed for Mid-Range pH Applications
Operates best within a pH range of 4 to 10, ideal for natural water and buffered samples
Durable and Lab-Friendly Design
PVC body with a 12 mm diameter and 120 mm insertion length for use in beakers and titration vessels
Temperature operating range: 0 to 40°C
Universal Connectivity
Equipped with a 1-meter coaxial cable and standard BNC connector for use with most ion meters or pH/ISE meters
Technical Specifications
| Parameter | Details |
|---|---|
| Ion Detected | Calcium (Ca²⁺) |
| Type | Polymer membrane; Half-cell |
| Measurement Range | 1 M to 3 × 10⁻⁶ M (40080 ppm to 0.12 ppm) |
| Slope | Approximately +28 mV/decade |
| Optimal pH Range | 4.0 to 10.0 |
| Temperature Range | 0 to 40°C |
| Body Diameter | 12 mm |
| Insertion Length | 120 mm |
| Body Material | PVC |
| Cable Length | 1 m (coaxial) |
| Connector | BNC |
Applications
Agriculture – Evaluate calcium in soil extracts, fertilizers, and irrigation water
Food & Beverage Industry – Analyze calcium content in milk, juices, mineral water, and other consumables
Water Treatment – Monitor calcium hardness in municipal or industrial water systems
Environmental Testing – Track calcium concentrations in rivers, lakes, and reservoirs
Academic & Research Labs – Ideal for calcium titration studies and educational demonstrations
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