Hanna HI4004 Calcium Half-Cell Ion Selective Electrode

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Hanna HI4004 Calcium Ion Selective Electrode – Polymer Membrane Half-Cell Sensor for Precise Calcium Ion Detection

The Hanna HI4004 Calcium Half-Cell Ion Selective Electrode is a polymer membrane ion-selective electrode (ISE) designed to measure calcium ion (Ca²⁺) concentrations in aqueous solutions. This half-cell configuration requires pairing with a reference electrode for a complete measurement system. It is ideal for environmental monitoring, agriculture, food and beverage quality control, and academic laboratories.

Capable of detecting calcium levels from 1 M to 3 × 10⁻⁶ M (40080 ppm to 0.12 ppm), the HI4004 provides stable, linear response across a practical pH range, making it an essential tool for routine calcium analysis in various matrices.

Key Features

Selective Calcium Ion Measurement

  • Reliable determination of free calcium ions in solution

  • Measurement range: 40080 ppm to 0.12 ppm (1 M to 3 × 10⁻⁶ M)

Polymer Membrane Technology

  • Incorporates a calcium-selective polymer membrane for consistent sensitivity and long lifespan

  • Delivers a slope of approximately +28 mV per decade of concentration

Designed for Mid-Range pH Applications

  • Operates best within a pH range of 4 to 10, ideal for natural water and buffered samples

Durable and Lab-Friendly Design

  • PVC body with a 12 mm diameter and 120 mm insertion length for use in beakers and titration vessels

  • Temperature operating range: 0 to 40°C

Universal Connectivity

  • Equipped with a 1-meter coaxial cable and standard BNC connector for use with most ion meters or pH/ISE meters

Technical Specifications

ParameterDetails
Ion DetectedCalcium (Ca²⁺)
TypePolymer membrane; Half-cell
Measurement Range1 M to 3 × 10⁻⁶ M (40080 ppm to 0.12 ppm)
SlopeApproximately +28 mV/decade
Optimal pH Range4.0 to 10.0
Temperature Range0 to 40°C
Body Diameter12 mm
Insertion Length120 mm
Body MaterialPVC
Cable Length1 m (coaxial)
ConnectorBNC

Applications

  • Agriculture – Evaluate calcium in soil extracts, fertilizers, and irrigation water

  • Food & Beverage Industry – Analyze calcium content in milk, juices, mineral water, and other consumables

  • Water Treatment – Monitor calcium hardness in municipal or industrial water systems

  • Environmental Testing – Track calcium concentrations in rivers, lakes, and reservoirs

  • Academic & Research Labs – Ideal for calcium titration studies and educational demonstrations

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